![]() Different types of LAVs are described with the emphasis on inversion tunneling (wagging) and internal rotation (torsion). In the review, we present an outline of the history and development of various theoretical approaches concerning molecules with LAVs. Molecules with LAVs have been of great interest for a very long time since their dynamic, geometry and molecular spectra were very often considered as a challenge. ![]() There are different types of LAVs among which the most common are inversion and internal rotation. Floppy molecules can be defined as molecules performing large amplitude vibrations (LAVs).
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